徐闻南山镇红树林沉积物及红树植物中重金属的累积特征与迁移规律

为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律，选取了徐闻南山镇红树林为研究对象，通过测定红树林沉积物及红树植物不同部位（根、茎、叶）的重金属质量分数，运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明：1）红树林沉积物重金属质量分数表现为铬（Cr）＞锌（Zn）＞镍（Ni）＞铜（Cu）＞铅（Pb）＞砷（As）＞汞（Hg）＞镉（Cd），为中等变异程度；除了镍（Ni）元素外，其余7种重金属未超过国家一级标准，除了铅（Pb）元素外，其余7种重金属均超过广东省土壤环境背景值，说明研究区沉积物中重金属具有一定的积累效应。2）沉积物中砷（As）、铜（Cu）、锌（Zn）、汞（Hg）、镍（Ni）、铬（Cr）富集因子值均＞1.5，说明受到轻微人为活动影响；各站位镍（Ni）富集因子值均＞5，结合研究区背景，反映了镍（Ni）受到自然和人为输入的共同影响。3）白骨壤体内重金属主要集中在根部，而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄，说明白骨壤对重金属的吸附能力比红海榄强。汞（Hg）集中分布在植物的叶片部位，且与其他重金属之间相关性不明显；推测汞（Hg）主要通过叶片吸收进入植物体内，与交通运输污染有关。4）不同红树植物对不同重金属富集能力各异，白骨壤对重金属的富集能力表现为：镉（Cd）＞砷（As）＞铜（Cu）＞锌（Zn）＞汞（Hg）＞铅（Pb）＞镍（Ni）＞铬（Cr），红海榄表现为：镉（Cd）＞铜（Cu）＞汞（Hg）＞锌（Zn）＞铅（Pb）＞砷（As）＞镍（Ni）＞铬（Cr）。白骨壤和红海榄对汞（Hg）的运移能力都较强；红海榄对镉（Cd）的富集能力和转运能力都较强，而白骨壤对镉（Cd）富集能力较强，转运能力却较弱，这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。     

Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

自然资源全要素自适应野外调查框架设计

针对自然资源全要素调查工作中分类标准不同、调查口径不同、调查方法不同，造成的各部门调查软件平台重复开发建设和调查数据结果地理信息特征表达不清晰等问题，本文结合自然资源全要素野外调查工作的实际需要，以山水林田湖草生命共同体为统一对象，构建了自然资源语义化特征模型，提出了表征不同自然资源类型的自适应野外调查方法，实现了灵活性高、性能优异的自然资源调查技术平台，形成了统一的自然资源全要素野外调查框架，可以有效提升多门类自然资源基础调查、专业调查、动态调查的能力与水平，为自然资源治理能力现代化提供了可靠技术保障。     

Asteroid families: evidence of ageing of the proper elements

In recent times it has been emphasized that the present kinematical structures of asteroid families should be evolved with respect to the original post-impact situations, according to numerical simulations performed taking into account also the previously neglected Yarkovsky effect. In this paper we show that also a “classical” approach based on an analysis of the current kinematical properties of families leads to conclude that the distributions of proper eccentricities and semimajor axes of family members exhibit evidence of an evolution. The importance of this approach is that it yields a fully independent and quantitative estimate of an evolutionary spreading of the proper elements. In particular, we find that the original post-impact families had to be on the average about twice more compact than the families we observe now, when considering family members down to about 5 km in size. This result can be used in future analyses to derive estimates of the ages of different families, and to better constrain the typical values of the ejection velocities of the fragments in family-forming events.     

A continuum‐discrete hydromechanical analysis of granular deposit liquefaction

A coupled continuum‐discrete hydromechanical model was employed to analyse the liquefaction of a saturated loose deposit of cohesionless particles when subjected to a dynamic base excitation. The pore fluid flow was idealized using averaged Navier–Stokes equations and the discrete element method was employed to model the solid phase particles. A well established semi‐empirical relationship was utilized to quantify the fluid–particle interactions. The conducted simulations revealed a number of salient micro‐mechanical mechanisms and response patterns associated with the deposit liquefaction. Space and time variation of porosity was a major factor which affected the coupled response of the solid and fluid phases. Pore fluid flow was within Darcy's regime. The predicted response exhibited macroscopic patterns consistent with experimental results and case histories of the liquefaction of granular soil deposits. Copyright © 2004 John Wiley & Sons, Ltd.     

Long-Period Variations of the Eccentricity Vector Valid also for Near Circular Orbits around a Non-Spherical Body

This paper studies the long period variations of the eccentricity vector of the orbit of an artificial satellite, under the influence of the gravity field of a central body. We use modified orbital elements which are non-singular at zero eccentricity. We expand the long periodic part of the corresponding Lagrange equations as power series of the eccentricity. The coefficients characterizing the differential system depend on the zonal coefficients of the geopotential, and on initial semi-major axis, inclination, and eccentricity. The differential equations for the components of the eccentricity vector are then integrated analytically, with a definition of the period of the perigee based on the notion of “free eccentricity”, and which is also valid for circular orbits. The analytical solution is compared to a numerical integration. This study is a generalization of (Cook, Planet. Space Sci., 14, 1966): first, the coefficients involved in the differential equations depend on all zonal coefficients (and not only on the very first ones); second, our method applies to nearly circular orbits as well as to not too eccentric orbits. Except for the critical inclination, our solution is valid for all kinds of long period motions of the perigee, i.e., circulations or librations around an equilibrium point.     

Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

青海省沙柳河南区有色金属矿成矿物质来源及矿床成矿模式探讨

本文简述了沙柳河南区有色金属矿床的基本特征。通过对成矿热液及成矿物质的来源与性质的研究,认为该矿床的成因类型为火山沉积—接触交代改造叠加型,进而探讨了该矿床的成矿模式。     

Ab initio infra-red spectra of iron-polycyclic aromatic hydrocarbon compounds: a model case

C₁₀H₆-Fe⁺ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C₁₀H₆-Fe⁺ systems are models for larger PAHs-Fe⁺ complexes, which are believed to play a key rôle in space chemistry.     

THE EFFECT OF DRAINAGE ON CHEMICALELEMENTS CONTENT OF MARSH

I INTRODUCTIONWetland has very important effect on retainingwater and against drought, regUlating climate, controlling soil erosion and so on ac. Today men often attachimportance to economic effect of wetland reclamation,but neglect and destroy other functions and effectswhich result in blind wetland development, a lot ofwetland degeneration. The area of freshwater wetland inthe 1950s was 134 x 10'ha, but in the 1970s 70% hadchanged into farmland (MITSCH, 1993). The area ofwetland in d…